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专利概况
专利名称 POLYFORMALDEHYDE THIN FILM AND PREPARATION METHOD THEREFOR
申请号 WOCN18110642 申请日
公开(公告)号 WO2020029426A1 公开(公告)日
申请(专利权)人 TANGSHAN KAILUAN CHEMICAL TECHNOLOGY CO LTD 发明人 WANG Yatao; MA Xiaofeng; LI Jianhua; LIU Lili; GUO Xuehua; LI Hongjuan; JIN Wang; YANG Dazhi; GUAN Lizheng
专利来源 国家知识产权局 转化方式
摘要

Disclosed by the present invention are a polyformaldehyde thin film and a preparation method therefor, the polyformaldehyde thin film comprising the following components in parts by weight : 96-98 parts of a polyformaldehyde resin, 0.5-2 parts of a nucleating agent, 0.5-1 parts of an antioxidant, and 0.5-1 parts of a formaldehyde absorbent. For the characteristics of high crystallization rate and fast crystallization speed of polyformaldehyde, a film blowing method is used to directly blow a melt extruded from a die of an extruder to form a film, thus overcoming the problem wherein necking and cracking easily occur during a stretching process, being beneficial in polyformaldehyde film forming, and having high processing efficiency and being easy to industrialize; a copolymerization unit -CH2-CH2-O- is introduced into the molecular chain of polyformaldehyde, and the proportion thereof is increased, which may effectively reduce the crystallization rate of a material such that same may easily form a film; a multi-stage air-cooled cooling mode is used to control the crystallization speed of polyformaldehyde and prevent local high crystallization; when the foregoing is used in combination with an application of a nucleating agent, spherulite size is reduced, crystal regularity and packing compactness are increased, inter-molecular force is increased, and the prepared polyformaldehyde film has excellent surface smoothness.

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